Aqua(2,2′-bipyridine-κ2N,N′)(2-methylmalonato-κ2O1,O3)copper(II) dihydrate
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چکیده
منابع مشابه
Aqua(2,2′-bipyridine)trifluoridochromium(III) dihydrate
The title compound, [CrF(3)(C(10)H(8)N(2))(H(2)O)]·2H(2)O, was prepared by the reaction of CrF(3) and 2,2'-bipyridine under hydrous conditions. The metal centre is coordinated in a distorted octahedral mode by two N atoms from the organic ligand, three F atoms and one O atom of a water molecule. . The crystal packing is stabilized by O-H⋯O and O-H⋯F hydrogen-bonding contacts, which form a one-d...
متن کامل4,4′-Bipyridine-1,1′-diium 2,3,5,6-tetrabromoterephthalate dihydrate
The title compound, C(10)H(10)N(2) (2+)·C(8)Br(4)O(4) (2-)·2H(2)O, consists of a tetra-bromo-terephthalate dianion, a 4,4'-bipyridinium dication and two solvent water mol-ecules. Crystallographic inversion centers are situated at the center of the aromatic ring of the dianion as well as at the midpoint of the carbon-carbon bond connecting the pyridine rings in the dication. In the crystal, inte...
متن کاملcatena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ2 N:N′] bis(perchlorate) 4,4′-bipyridine disolvate dihydrate]
In the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](ClO(4))(2)·2C(10)H(8)N(2)·2H(2)O}(n), slightly distorted octa-hedrally coordinated Co(II) ions situated on inversion centers are linked into polycationic chains through 4,4'-bipyridine tethering ligands. These are connected into supra-molecular layers by hydrogen bonding involving aqua ligands, perchlorate anions and uncoordinated water mol-...
متن کاملPoly[[(2,2′-bipyridine)(μ3-2-sulfonatobenzoato)lead(II)] dihydrate]
In the title compound, {[Pb(sbc)(bpy)]·2H(2)O}(n) [bpy is 2,2'-bipyridine (C(10)H(8)N(2)) and sbc is the 2-sulfonatobenzoate dianion (C(7)H(4)O(5)S)], the Pb(II) ion is bonded to four O atoms including carboxyl-ate and sulfonate from three sbc dianions, and two N atoms from a chelating 2,2'-bipyridine ligand. The sbc ligand acts as a μ(3)-bridging ligand by one O atom of the sulfonate group and...
متن کامل(2,2′-Bipyridine)bis(3-carboxypyrazine-2-carboxylato)copper(II) dihydrate
The title six-coordinated distorted octa-hedral complex, [Cu(C(6)H(3)N(2)O(4))(2)(C(10)H(8)N(2))]·2H(2)O, consists of two 3-carboxy-pyrazine-2-carboxyl-ate anions and one 2,2'-bipyridine ligand. There is a twofold rotation axis positioned at the Cu(II) center. The N atoms of the pyrazine ring occupy the axial positions and two proton-transferred O atoms of tbe acid together with the two N atoms...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812024889